Sodium Hydride Catalyzed Tishchenko Reaction

http://onlinelibrary.wiley.com/store/10.1002/ejoc.201001294/asset/supinfo/ejoc_201001294_sm_miscellaneous_information.pdf?v=1&s=823338044579c670af049dbc11d92eacc01a42a8



European Journal of Organic Chemistry

Volume 2010Issue 36pages 6904–6907December 2010

 

The use of catalytic amounts of sodiumhydride as an efficient promoter for the dimerization of aromatic and even heteroaromatic aldehydes under standard laboratory conditions is reported. A range of substituted aromatic and heteroaromatic aldehydes was converted, and the corresponding esters were obtained in good to excellent yields even on a multigram scale.

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